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CORM-EDE1: A Highly Water-Soluble and Nontoxic Manganese-Based photoCORM with a Biogenic Ligand Sphere
[Mn(CO)5Br] reacts with cysteamine and 4-amino-thiophenyl with a ratio of 2:3 in refluxing tetrahydrofuran to the complexes of the type [{(OC)3Mn}2(μ-SCH2CH2NH3)3]Br2 (1, CORM-EDE1) and [{(OC)3Mn}2(μ-SC6H4-4-NH3)3]Br2...
PublicationsGold nanocubes – direct comparis on of synthesis approaches reveals the need for a microfluidic synthesis setup for a high reproducibility
The production of non-spherical gold nanoparticles is a rather complex process and requires a multistep synthesis including surface blocking detergents such as CTAC and CTAB (cetyltrimethylammoniumchloride;...
PublicationsAnalysis of optical properties of spherical metallic nanoparticles for effective absorption of solar radiation and their heating
The investigations and the use of nanoparticles as photothermal agents in solar and photonic nanotechnology represent a fast growing area of research and applications. Potential benefits include the possibility...
PublicationsRaman imaging of changes in the polysaccharides distribution in the cell wall during apple fruit development and senescence
During on-tree ripening, the pectin distribution changed from polydispersed in cell wall to cumulated in cell wall corners. During apple storage, the pectin distribution returned to evenly dispersed along...
PublicationsEfficient energy transfer and metal coupling in cyanide-bridged heterodinuclear complexes based on (bipyridine)(terpyridine)ruthenium(II) and (phenylpyridine)iridium(III) complexes
We report a series of cyanide-bridged, heterodinucleariridium(III)−ruthenium(II) complexes with the generalized formula [Ir((R2)2-ppy)2(CN)(μ-CN)Ru(bpy)-(tpy-R1)]PF6 (ppy = 2-phenylpyridine, bpy = 2,2′-bipyridine,and...
PublicationsA comprehensive comparison of dye-sensitized NiO photocathodes for solar energy conversion
We investigated a range of different mesoporous NiO electrodes prepared by different research groups and private firms in Europe to determine the parameters which influence good quality photoelectrochemical...
PublicationsElucidation of the CO-Release Kinetics of CORM-A1 by Means of Vibrational Spectroscopy
CO-releasing molecules (CORMs) are developed for investigations of the interaction between the signaling molecule carbon monoxide (CO) and cells or tissue. Prior to their application these molecules require...
PublicationsLight sheet Raman micro-spectroscopy
Raman spectroscopy is a laser spectroscopic method which reveals detailed chemical information about a sample. Pointwise scanning produces chemical maps of heterogeneous samples such as biological tissue...
PublicationsNanodrawing of Aligned Single Carbon Nanotubes with a Nanopen
Single-Walled Carbon nanotubes (SWCNTs) are pivotal for both fundamental and applied research in nanotechnology. They are significant as molecular electrical building blocks that can be used for interconnects,...
PublicationsDichroic atomic vapor laser lock with multi-gigahertz stabilization range
A new version of a dichroic atomic vapor laser lock (DAVLL) system is presented, which exploits buffer-gas-filled millimeter-scale vapor cells. This µ-DAVLL system offers similar stability as achievable...
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