Dispersion analysis with inverse dielectric function modelling

in: Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy (2016)
Mayerhöfer, Thomas G.; Ivanovski, Vladimir; Popp, Jürgen
We investigate how dispersion analysis can profit from the use of a Lorentz-type description of the inverse dielectric function. In particular at higher angles of incidence, reflectance spectra using p-polarized light are dominated by bands from modes that have their transition moments perpendicular to the surface. Accordingly, the spectra increasingly resemble inverse dielectric functions. A corresponding description can therefore eliminate the complex dependencies of the dispersion parameters, allow their determination and facilitate a more accurate description of the optical properties of single crystals.

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