Photochemical Fate: The First Step Determines Efficiency of H-2 Formation with a Supramolecular Photocatalyst

in: Angewandte Chemie-International Edition (2010)
Tschierlei, Stefanie; Karnahl, Michael; Presselt, Martin; Dietzek, Benjamin; Guthmuller, Julien; Gonzalez, Leticia; Schmitt, Michael; Rau, Sven; Popp, Jürgen
The color of the incident light determines the efficiency of the hydrogen evolution mediated by a supramolecular photocatalyst. This finding demonstrates the importance of the Franck–Condon point in artificial photosynthesis systems and should have an impact on their design.

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