Visible Light-Activated Biocompatible Photo-CORM for CO-release with Colorimetric and Fluorometric Dual Response

in: Polyhedron (2019)
Reddy, Gandra Upendar; Hoffmann, Patrick; Steinmetzer, Johannes; Askes, Sven H. C.; Kupfer, Stephan; Görls, Helmar; Liu, Jingiing; Gräfe, Stefanie; Neugebauer, Ute; Schiller, Alexander
We introduce a colorimetric as well as fluorometric dual response CO-releasing molecule as Mn(I) tricarbonyl complex with a nitrobenzodiazole (NBD) fluorophore. DFT and TD-DFT studies corroborate that extended conjugation in the principal ligand frame will help to release CO at low energy radiation. A very low toxicity of NBD-CORM was observed against LX-2 and HepaRG® human cell lines.

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