A superconducting charge-flux qubit coupled to a high-Q tank circuit was studied in a low-frequency electric field. A fine structure of the multiphoton resonance lines and quantum interference effects associated with the excitation of a quasi-two-level system due to the Landau–Zener–Stückelberg tunneling was observed. The results obtained for multiphoton resonant excitations and low-frequency oscillations of the average occupation of quantum levels were compared using different parameters of the measuring circuit. The mechanism responsible for the fine structure of resonance lines was considered. The method to measure the impedance arising in the tank circuit due to the oscillations of the superconducting current in the qubit and the main sources of decoherence were discussed.